Free energy of metal-organic framework self-assembly
نویسندگان
چکیده
منابع مشابه
Directional self-assembly of a colloidal metal-organic framework.
Materials science is at an early stage of learning to employ anisotropic interaction in self-assembly. One important approach towards this goal involves the study of nm-sized particles, but we note two limitations: first that this is a rather special case as the range of inter-particle interaction in suspensions is typically likewise nm in size, and secondly that the diffraction limit precludes...
متن کاملMetal-organic framework materials as nano photocatalyst
Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
متن کاملMetal-organic framework materials as nano photocatalyst
Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
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The spontaneous assembly of molecular building blocks into supramolecular and giant molecular assemblies occurs in nature as for instance in cells with the assembly of lipid bilayer membranes. Taking advantage of these bio-synthesis strategies to create novel self-assembled multifunctional nanostructured in which pre-designed and functionalized molecules are self-assembled into supramolecular a...
متن کاملSelf-assembly of metal-organic hybrid nanoscopic rectangles.
The combination of an amide containing a linear ligand (L1) and an organometallic molecular "clip" (clip-1) leads to the self-assembly of a Pt4 nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle-1) incorporating amide functionality. A complementary approach was also followed to prepare a Pd(II)-based molecular rectangle (rectangle-2) by reaction of ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2019
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.5063588